THOMAS W. EAGAR: MIT Theses Supervised

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(The links from the thesis titles lead to electronic copies. For theses without electronic versions, see MIT Libraries for information on how to obtain them.)

"Mechanical behavior of dip-brazed aluminum sandwich panels," Brian P. Hohmann, Thesis (S.M.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp. 161, 2007.

Abstract:An experimental study was carried out to determine the mechanical behavior of  sandwich panels containing cellular cores of varying shape. Compression and four  point bend tests were performed on sandwich panels with square and triangular  honeycomb cores. These honeycombs were made of perforated aluminum sheet of  repeating diamond and hexagonal patterns. The sandwich panel assemblies were  joined via dip brazing. Defects were introduced into some panels to quantify the  effect on strength and stiffness. Hybrid sandwich panels, consisting of foam  material in the void spaces of the square and triangular cells were evaluated for  the effect on the defect tolerance of the structures. The results showed that  sandwich panels with diamond shaped cores had compressive strengths approximately  four times greater than hexagonal shaped cores. In four point bending the diamond  cores were approximately twice as stiff as cores made from hexagonal patterned  sheet. The introduction of defects lowered strength by about 30% for diamond  cores in compression, and about 15% for hexagonal cores. In four point bending  this strength reduction was not as significant due to shear stresses damaging  periodicity at a faster rate than in compression. The use of foam within the cells resulted in higher absolute peak compression and  flexure loads, however the Load/Density ratios demonstrated cases where the added  weight of the foam did not result in a better panel. A difference of nearly an  order of magnitude between the highest and lowest compressive and flexure loads  is evident when the presence of defects and foam are taken into account.

"Sintering and joining of low temperature co-fired tungsten and aluminum oxide, " Yuttanant Boonyongmaneerat, Thesis (S.M.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Christopher A. Schuh and Thomas W. Eagar, pp. 189, 2006. 

Abstract:Conventional methods used to fabricate co-fired tungsten/alumina composites usually rely on high temperature processing (>1500C). As it would be beneficial or even necessary for some applications to produce such composites at relatively low firing temperatures, low-temperature processing techniques and the attendant knowledge of processing-property relationships need to be developed. In this thesis, a set of experiments and simulations are performed to obtain a better understanding of sintering and joining of the tungsten/alumina system processed at temperatures near or below 12000C. The technique of activated sintering for tungsten is investigated, whereby a minimal content of additives enables low firing temperatures through a change in the sintering mechanism for tungsten. Tungsten compacts produced by this method are found to sinter only to the "initial stage" and are characterized by high residual porosity level. Hardness and fracture toughness of such partially-sintered materials are examined experimentally and analytically, and dependence of mechanical properties on the relative particle neck size is observed. Various studies are carried out to examine both fundamental and practical aspects of joining co-fired tungsten/alumina. First, contributions to adhesion of co-sintered bilayers are studied where the properties of the tungsten layer are controlled using the process of activated sintering. Using a bending delamination test, improvements in sintered density of tungsten are found to increase the adhesive strength of the system only up to a point, beyond which shrinkage mismatch compromises the intrinsic toughness of the interface. A study of low-temperature co-fired tungsten/alumina is then focused on composite shells for an investment casting application. The influences of various processing parameters in a slurry-based route on the sintering and adhesion properties of tungsten/alumina are investigated. Binder content, stucco sand application, and powder characteristics are among the parameters found to critically control the quality of tungsten/alumina shells produced. Finally, the feasibility of several joining strategies, which involve the use of chemical additives, is examined on co-fired tungsten/alumina compacts processed at low temperatures. Some bonding techniques are verified to help improve the bonding of the co-sintered composites.

"Materials production economics : an examination of the variables and relationships that drive materials production and recycling in the world economy, " Yao-Chung King, Thesis (S.B.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp.29, 2006.

"Measurement and control of brake pedal feel quality in automobile manufacturing, " Jeffrey T. Cerilles,  Thesis (M.B.A.)--Massachusetts Institute of Technology, Sloan School of Management; and, (S.M.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering; in conjunction with the Leaders for Manufacturing Program at MIT, supervised by Thomas W. Eagar and Charles H. Fine, pp.60, 2005.

"Improving maintenance work flow processes in a volatile assembly factory environment : maintenance people and processes, spares inventory, and equipment reliability, " H. Ryan Chase, Thesis (M.B.A.)--Massachusetts Institute of Technology, Sloan School of Management; and, (S.M.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering; in conjunction with the Leaders for Manufacturing Program at MIT, supervised by Thomas W. Eagar and Roy E. Welsch, pp.45, 2005.

"Re-sourcing manufacturing processes in metal forming operations, " Heath M. Holtz, Thesis (M.B.A.)--Massachusetts Institute of Technology, Sloan School of Management; and, (S.M.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering; in conjunction with the Leaders for Manufacturing Program at MIT, supervised by Thomas W. Eagar and Stephen C. Graves, pp. 76, 2005.

"Beating the system: accelerating commercialization of new materials, " C. S. Musso, Thesis (Ph. D.)--Massachusetts Institute of Technology, Engineering Systems Division, supervised by Thomas W. Eagar, 2004. 

Abstract: Over the past century, materials have faced notoriously long delays between invention and commercialization. These delays make private investment very difficult, and can prevent good materials from reaching markets. A systematic exploration of the commercial histories of major commodity thermoplastics was performed, which showed that these delays were attributable to technical deficiencies in materials and obstacles in the application value chains. Contrary to popular wisdom, material costs, competitive materials, and serendipity were much smaller factors in commercialization delay. The factors that led to insertion of plastics into applications were different than the factors that led to post-insertion growth. The major plastics showed a characteristic pattern of commercialization. First, they entered simple, small applications in which they solved new problems. They then progressed to achieve insertion in a single major application, which they continue to dominate today. Having established themselves with this application, they found insertion in a wide range of large applications. The commercialization pattern can be explained in large part by the concept of switching costs. As knowledge of a material increases, switching costs are reduced; as value chain complexity increases, switching costs increase. The earliest applications required little understanding of plastics and had simple value chains, so switching costs were low, corresponding to fast commercialization. Later applications had more complex value chains and required much more detailed understanding of the failure modes and processing parameters of the material, corresponding to high switching costs and slow commercialization. Materials can be deployed into many markets. By strategically selecting application markets, materials producers can significantly improve the probability that new materials will be adopted and can shorten the period of commercialization. Early markets should be selected based on the ability of the material to solve unique problems and the simplicity of the application value chain. When market selection is not an option, materials producers can integrate forward in the value chain to shorten commercialization times, but capital requirements are very high. Once integrated into an application, the safest competitive position for materials is to be the lowest cost option that meets the exact needs of the application.

"Delivery optimization for a make to order custom wire mill, " Andrey L. Slivinskiy, Thesis (M.B.A.)--Massachusetts Institute of Technology, Sloan School of Management; and, (S.M.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering; in conjunction with the Leaders for Manufacturing Program at MIT, supervised by Donald Rosenfield and Thomas W. Eagar,  pp. 73, 2005.

"Low temperature transient liquid phase bonding of copper, " Joel C. Williams, Thesis (S.M.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp. 34, 2005

Abstract: This thesis describes a Pb-free solder alternative that is capable of fluxless bonding. The main advantage of this process is that it offers the benefits of low fabrication temperature (125¡C) while producing a joint capable of withstanding low stresses at very high service temperatures (300¡C+). The ternary alloy system of Bi-In-Sn was investigated in the bonding of copper substrates. All bonds were made at 125¡C with 25psi of fixturing pressure. Primary solidification was observed in as little as 15 minutes. The mechanical properties of the joints were shear tested both at room temperature and at 1000C to simulate a conventional service environment. With sufficient dwell time (-250h), joints would not fail in shear even at stresses that caused significant substrate deformation. Scanning electron microscopy was used to examine the joints and the evolution of the diffusion process.

 

"Commercial application of aluminum honeycomb and foam in load bearing tubular structures,"Stefano Bartolucci, Thesis (S.M.)--Massachusetts Institute of Technology, Department of Materials Science and Engineering, supervised by Lorna Gibson and Thomas W. Eagar, 2004.

Abstract: Small dimension engineering tubular structures subjected to a complex load system are designed like hollow circular shells. For minimum weight design, the ratio between the shell radius and the thickness has to be as large as possible, but its maximum value is limited by the onset of local buckling. Tubular natural structures subjected to a complex load system have often an outer shell of solid material supported by a low density, compliant core, which makes them more resistant to local buckling. Biomimicking of natural constructions offer the potential to improve the design of small diameter tubular engineering structures. Here, the fabrication technology of biomimicked engineering tubular structures integrating aluminum foam or honeycomb as core material is discussed. A viability analysis is presented including technical performance, cost, utility, and risk assessments. Aluminum compliant core shells have potential for substituting CFRP and aluminum tubular structures in aerospace and high-level sport applications. The case of sailboat masts was considered in detail. Results of our analysis proved that use of honeycomb as core material can lead to a significant reduction of the mast weight. Business opportunities based on this application are discussed.

"Thermodynamics and kinetics of ceramic/metal interfacial interactions," R. Arroyave, Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp.248, 2004.
Abstract: Ceramic/metal interfaces occur in a great number of important applications, such as ceramic/metal composites, microelectronics packaging, ceramic/metal seals, and so forth. Understanding the is proposed. Because of the importance of zirconia-based ceramics in increasingly important applications such as structural composites, thermal barrier coatings and Solid Oxide Fuel Cells, it was decided to illustrate the concepts developed in this thesis through the study of the interactions between zirconias and active metals. Semi-empirical thermodynamic models of all the phases likely to take part in the ceramic/metal interfacial interactions studied were developed. Phase diagram data and thermochemical in complex interfacial reactions occurring during the active metal brazing of zirconia-based ceramics. By using simple one-dimensional interdiffusion simulations, it was demonstrated that the base metal in ceramic/metal joints plays an essential role in determine the thermochemical interactions at the ceramic/metal interface during ceramic/metal joining operations. In general it was found that, using all these techniques,it was possible to explain diffusion paths and reaction sequences observed in a great number of zirconia/active-metal systems, both in the solid and in the liquid states. In many cases, the morphology of the reaction layers formed at ceramic/metal interfaces determine their final properties. To address this problem, empirical thermodynamic models of the likely reaction products at zirconia/metal interfaces were coupled to kinetic models using the diffuse-interface formalism.

"Addressing equipment set-up time and manufacturing cost through real time inline inspection in tantalum wire manufacturing," C. A. Gonzalez, Thesis (M.B.A.)--Massachusetts Institute of Technology, Sloan School of Management; and, (S.M.)--Massachusetts Institute of Technology, Dept. of Mechanical Engineering; in conjunction with the Leaders for Manufacturing Program at MIT, supervised by Roy E. Welsch and Thomas W. Eagar, pp. 53, 2004
Abstract: For this study, a novel wire inspection system was developed to detect surface defects and monitor diameter real-time during the final wire drawing operation. Throughout his work, it was proven that the new inspection system was able to catch common wire defects under manufacturing conditions (wire speed). Furthermore, defect density limits were defined based on data collected during this study. A production version of the wire inspection system was jointly developed with the equipment supplier and an order was placed for three complete systems to be installed in all final draw machines. Increased competition and poor economic conditions forced the manufacturer to place an unprecedented focus on decreasing manufacturing costs. The wire inspection system reported in this thesis was developed with the objective of increasing productivity at the most critical operation in the factory; final wire drawing.

"Metallographic study of gamma - gamma prime structure in the Ni-based superalloy GTD111," A. Kountras, Thesis (S.M..)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, 2004.
Abstract: The potential for land-based turbine buckets material rejuvenation presents a significant commercial and scientific interest. Ni-based superalloy GTD111 is used at a number of GE-manufactured power generation turbines. The outstanding creep resistance features of Ni-based superalloys can be attributed to a large extent, to the gamma prime ([gamma]') precipitates found within the FCC [gamma]-matrix. Service-induced material degradation mainly involves coarsening and shape trans conditions, leading to useful conclusions concerning material degradation as a result of high-temperature service exposure. In addition, microstructural trans GTD111 microstructure. Finally, the measurements were examined for correlation with existing [gamma]' particle coarsening theory, by calculating and evaluating the metal service temperature during service. A satisfactory correlation exists.

"Solving a corrosion quality problem at a major US automaker," J. C. Wallach, Thesis (M.B.A.)--Massachusetts Institute of Technology, Sloan School of Management; and, (S.M.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering; in conjunction with the Leaders for Manufacturing Program at MIT, supervised by Thomas W. Eagar and Thomas Roemer, 2004.
Abstract: This project addresses a corrosion quality problem at an automaker. The problem, hem flange corrosion, involves the appearance of red rust along edges of closure panels (doors, hoods, deck lids, etc) after three to four years in service. This project focuses on finding a solution for a particular new model. The project contains two parts: a technical treatment of hem flange corrosion and an organizational analysis. The technical discussion includes a root-cause analysis, failure analysis of past solution attempts, benefit/cost analysis of potential solutions, and technical recommendations. The organizational discussion examines why this automaker was challenged with implementing a solution.

"Smoothing of pipe system completion processes in a shipyard environment," S. J. Zojwalla, Thesis (S.M.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering; and, (M.B.A.)--Massachusetts Institute of Technology, Sloan School of Management; in conjunction with the Leaders for Manufacturing program at MIT, supervised by Thomas W. Eagar and Arnold Barnett, 2004.
Abstract: Due to a number of different production issues, the manufacture of template pipes is often delayed. These delays hold up pipe system completion on board the ships in production and can delay payments from the Ministry of Defense. In order to improve the production of template pipes, a number of changes are recommended to the pipe production processes overall. These include improvements in production planning, along with changes in procurement and scheduling methods. These changes in production methods will result in more material available when it is needed and will therefore improve the manufacture of template pipes. Additionally, they will improve the overall availability of pipes when needed as well as reducing inventory of finished pipes and decreasing the amount of rework. A number of other recommendations to improve the overall pipe manufacture process are also identified, including changes in performance measures, production planning, and other potential areas of improvement.

"Chemistry of airborne particles from metallurgical processing," N. T. Jenkins, Thesis (Ph.D.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar pp. 189, 2003.
Abstract: Airborne particles fall into one of three size ranges. The nucleation range consists of nanoparticles created from vapor atom collisions. The decisive parameter for particle size and composition is the supercooling of the vapor. The accumulation range, which comprises particles less than 2 micrometers, consists of particles formed from the collision of smaller primary particles from the nucleation range. The composition of agglomerates and coalesced particles is the same as the bulk vapor composition. Coarse particles, the composition of which is determined by a liquid precursor, are greater than 1 micrometer and solidify from droplets whose sizes are controlled by surface, viscous, and inertial forces. The relationship between size and composition of airborne particles could be seen in welding fume, a typical metallurgical aerosol. This analysis was performed with a cascade impactor and energy dispersive spectrometry with both scanning electron microscopy (SEM-EDS) and scanning transmission electron microscopy (STEM-EDS). Other methods for properly characterizing particles were discussed. In the analysis, less than 10% of the mass of fume particles for various types of gas metal arc welding (GMAW) were coarse, while one-third of flux cored arc welding (FCAW) fume particles were coarse. Coarse particles had a composition closer to that of the welding electrode than did fine particles. Primary particles were not homogeneous. Particles larger than the mean free path of the carrier gas had the same composition as that of the vapor, but for particles 20 to 60 nanometers, smaller particles were more enriched in volatile metals than larger particles were. This was explained by the cooling path along the bubble point line of a binary phase diagram. Particles were not necessarily homogenous internally. Because nanoparticles homogenize quickly, they may form in a metastable state, but will not remain in that state. In this analysis, the presence of multiple stable immiscible phases explains this internal heterogeneity. The knowledge contained herein is important for industries that depend on the properties of nanoparticles, and for manufacturing, where industrial hygiene is important because of respirable particle by-products, such as high-energy-density metallurgical processing.

"Friction stir processing for superplasticity and other applications," L. B. Johannes, Thesis (M. Eng.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp. 50, 2003.
Abstract:  Friction stir welding is a recent welding technology that had expanding the capabilities of welding aluminum alloys. From this process, it was discovered that the microstructural properties of a metal could be altered with a single pass of the tool, and from this the area of friction stir processing can be expanded beyond welding. While friction stir processing is a new field of research, many areas of study have been discovered including the area of friction stir superplasticity. Using the small grain size achieved by the process and the high grain boundary misorientation angle, it has been found that friction stir processing is capable of creating high strain rate superplasticity in aluminum alloys. This study evaluates the technology of friction stir processing. In detail, the study examines the applications, competing technologies, intellectual property, and the start of the business aspects of the technology. In summary, it was found that the main applications for the technology are in the automotive and aerospace industries. The largest competing technology generally uses a six-step process that does not allow for high strain rates and thick sections. Both of these can be achieved by friction stir processing. Key patents in the area were also examined. In the business evaluation it was determined that the technology would likely be applied first in the automotive industry and used by a major automotive manufacturer in order to reduce costs. Overall, friction stir superplasticity appears to have a lot of potential for future superplasticity applications.

"From art to science : improving production and sales of colored chocolate," C. S. Musso, Thesis (S.M.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering; and, (M.B.A.)--Massachusetts Institute of Technology, Sloan School of Management; in conjunction with the Leaders for Manufacturing Program at MIT, supervised by Thomas W. Eagar and Thomas Roemer, pp. 102, 2003.

"Welded repair and maintenance in the space environment," V. Nikou, Thesis (Nav.E.)--Massachusetts Institute of Technology, Dept. of Ocean Engineering; and, (S.M.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, upervised by Koichi Masubuchi, Patricio F. Mendez and Thomas W. Eagar, pp. 113, 2003.

"Development and manufacture of continuous strand metal matrix composites," C. S. Musso, Thesis (S.M.)--Massachusetts Institute of Technology, Engineering Systems Division, Technology and Policy Program, supervised by Thomas W. Eagar, pp.121, 2002.

"A framework for designing interlayers for ceramic-to-metal joints," J.-W. Park, Thesis (Ph.D.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp. 168, 2002.
Abstract: Engineering ceramics have become widely used as structural materials due to their excellent mechanical and thermal properties at high temperature. In most structural applications, ceramics are integrated as critical components in a system that is largely metallic and have to be joined frequently to metals. During joining processes, residual stresses are induced in the joints due to the large differences in physical properties between ceramics and metals, which degrades the mechanical integrity of the joints. This thesis proposes improved design rules for interlayers used to accommodate residual stresses in ceramic-to-metal joints. Efforts have been made on developing theoretical understanding of the important factors affecting residual stresses. Using Finite Element Method (FEM) simulations and Order of Magnitude Scaling (OMS), our understanding could be summarized and generalized as closed-form analytical equations. In these equations, the accumulated elastic strain energy in the ceramic has been used as a more reliable metric for quantifying residual stresses and predicting failure stress. The equations provide a useful functional relationship between the strain energy, material properties, and joint geometry. To the best of our knowledge, they are the first analytical expressions explaining the plasticity effect in the ceramic-to-metal joints. In these equations, the strain energy normalized by the scaling factor consisting of dominant parameters is a linear function of dimensionless groups of secondary important parameters. The physical implication of each dimensionless group also has been clearly defined. Based on analytical equations, improved interlayer design rules have been proposed and verified experimentally. Among the dimensionless groups, 4), the ratio of CTE difference between the interlayer and each base material, represents the stress distribution in the interlayer and its effect on plastic de of an interlayer cannot be modified in practice, the use of additional interlayers can redistribute the residual stresses in the interlayer and exploit the ductility of the interlayer more efficiently. Based on this fact, use of rigid layers with increasing CTE away from the ceramic interface and insertion of ductile layers between each rigid layer is proposed as a better multiple interlayer design than multiple interlayers with graded CTE. In the equations, strain energy increases proportional to the joint radius cubed. Controlled porosities have been incorporated in the interlayer by patterning to reduce the joint area, hence to decrease the strain energy. Shear test results confirmed our design rules for multiple and patterned interlayers. For patterened interlayers, an optimized level of porosity in the interlayer without interface weakening could be found. Although the effects of all the parameters cannot be considered, experimental results confirmed that our understanding addresses dominant parameters for joint strength with simple equations that provide a useful viewpoint in designing ceramic-to-metal joints ...

"Manganese and Health in the Welding Environment," M. C. Balmforth, Thesis (S.M.)-Massachusetts Institute of Technology, Dept. of Materials Science and Engineering; and, (S.M.)--Massachusetts Institute of Technology, Engineering Systems Division, Technology and Policy Program, supervised by Thomas W. Eagar, pp. 95, 2001.
Abstract: There are approximately 0.5 million full-time welders in the U.S., with even more workers welding intermittently. Over the past thirty years there has been increased interest in the effects of welding fume on the health of these workers. Manganese is an essential element in the making of all steel products and steel welding electrodes and is, therefore, present in fume that is generated during welding of these materials. Manganese is essential to humans in small amounts, but in larger amounts it is a neurotoxin and causes manganism, a disease with symptoms similar to Parkinson's disease. Manganese has been reported to cause adverse health effects in industries such as paint production, battery production, and manganese ore mining. Occupational exposure limits for manganese have been developed based on these industries, and the lowest limit, the TLV" established by the American Conference of Governmental Industrial Hygienists, is a source of concern to the welding industry. This thesis attempts to answer the question, "Is the current exposure limit for manganese feasible and does it make sense for the welding industry?" It does this by evaluating whether there is evidence of manganese harm to welders, and evaluating the issues associated with this topic. Calculations show that during an eight-hour shift at current acceptable standards, it is not possible for a welder to ingest enough manganese from the welding environment to cause manganism. There is also evidence that welding fume, which contains iron as well as manganese, carries its own antidote to manganism. A hypothesis suggests that manganese in welding fume, due to affects associated with iron, may not be transferred in harmful amounts across the blood-brain-barrier (BBB). Economic costs to industry would be substantial in meeting the lower exposure limit. The evidence suggests that, at the current permissible level of exposure to total welding fume, the risk of a welder contracting manganism is essentially zero and the economic costs that would be involved with the lower TLV@ are not justified.

"Spheroidization of iron powder," B. C. Hunsaker, Thesis (S.M.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering; and, (S.M.)--Massachusetts Institute of Technology, Engineering Systems Division, Technology and Policy Program, supervised by Thomas W. Eagar, pp. 95, 2001.

"Developing a strategy for change in a former "mom and pop" job shop," J. Sullivan, Thesis (M.B.A.)--Massachusetts Institute of Technology, Sloan School of Management; and, (S.M.)--Massachusetts Institute of Technology, Dept. of Chemical Engineering; in conjunction with the Leaders for Manufaturing Program at MIT, Janice A. Klein and Thomas Eagar, pp. 50, 2001.

"Reactive brazing of zirconia to nickel-based super alloys," R. Arroyave, Thesis (S.M.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp. 98, 2000.

"Using postponement to move from job-shop to a mixed MRP/job shop environment," T. J. Carroll, Thesis (M.B.A.)--Massachusetts Institute of Technology, Sloan School of Management; and, (S.M.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering; in conjunction with the Leaders for Manufacturing Program, Massachusetts Institute of Technology, supervised by Stephen C. Graves and Thomas W. Eagar, pp. 47, 2000.

"Development of a sampling strategy for inspecting multi-layer printed circuit boards," M. D. Falcon, Thesis (S.M.)--Massachusetts Institute of Technology, Sloan School of Management; and, (S.M.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, Thomas W. Eagar and Roy E. Welsch, pp. 70, 2000.

"Co-ordinating flows across supply chains in the low volume gas turbine industry," Miriam Park, Thesis (S.M.)--Massachusetts Institute of Technology, Sloan School of Management; and, (S.M.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering; in conjunction with the Leaders for Manufacturing Program, Massachusetts Institute of Technology, supervised by Donald B. Rosenfield and Thomas W. Eagar, pp.80, 2000.

"Repair of partially penetrated weld joints in copper-nickel seawater piping on naval ships," Alan A. Rechel, Thesis (S.M.)--Massachusetts Institute of Technology, Dept. of Ocean Engineering; and, (S.M.)--Massachusetts Institute of Technology, Dept. of Materias Science and Engineering, supervised by Thomas W. Eagar and David V. Burke, p.133, 2000.

"Redefining manufacturing quality control in the electronics industry," Maureen Fresquez Simington, Thesis (S.M.)--Massachusetts Institute of Technology, Sloan School of Management; and, (S.M.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering; in conjunction with the Leaders for Manufacturing Program, Massachusetts Institute of Technology, supervised by Thomas W. Eagar and Roy E. Welsch, pp.104, 2000.

"Definition and implementation of a visual inventory management system," M. A. Kimber. Thesis (S.M.)--Massachusetts Institute of Technology, Sloan School of Management; and, (S.M.)--Massachusetts Institute of Technology, Dept. of Mechanical Engineering, supervised by Stephen C. Graves and Thomas W. Eagar, pp. 71, 1999.
Abstract: Companies today often look to improved inventory management as a means to lower costs and increase their ability to consistently meet customer needs. Research was conducted at Alcoa (Shanghai) Aluminum Products Co., Ltd. (ASAP) in Shanghai, China to determine a framework that might be used to define and implement a visual inventory management system in a foil mill, The framework proposed is founded on 1 ) understanding the current material and information flows and developing reasons why inventory exists, 2) consolidating rolling and annealing schedules, identifying key specifications, determining necessary inventory levels, and defining a pull system, and 3) creating an environment where people are included in the change process and educated in the principles upon which the visual inventory management system is based, The framework proposed enabled a pull production system to be implemented at ASAP in the cast shop and rolling area in approximately 6 months. It is anticipated that total WIP and finished goods inventory levels will be decreased from 2000T to 1600T, average coil manufacturing time will be reduced from approximately 19 days to 15.5 days, and delivery performance will be improved.

"Carbide formation in a nickel-based superalloy during electron beam solid freeform fabrication," J. E. Matz, Thesis (Sc.D.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, 1999.
Abstract: The Electron Beam Solid Freeform Fabrication process involves the use of an electron beam to make near-net-shape metal parts without the need for tooling. Material in wire form is fed into a melt pool maintained on the surface of the part by the electron beam and a positioning system causes the deposition to occur in a line-by-line, layer-by-layer fashion. Solidification occurs at a high rate, forming a fine dendritic microstructure and fine dispersion of primary carbides. This structure is believed to be optimal for the manufacture and safe use of certain nickel-base superalloy parts, notably turbine disks. The growth of carbide particles from the liquid during EBSFF processing of Alloy 7 18 has been modeled assuming diffusion control and isolated spherical carbides. The driving force for growth is assumed to increase in a linear manner throughout the temperature range of carbide precipitation. The model predicts the maximum carbide size as a function of EBSFF operating parameters and the alloy niobium and carbon levels. For the material and conditions used experimentally in this work, the model predicts a maximum diameter of approximately 1.0 um. The maximum carbide size will become an important determining factor for turbine disk performance when oxide and nitride inclusions have been eliminated through improved melt practices. To illustrate this, the low-cycle fatigue life as a function of carbide size for a standard specimen geometry was calculated. Extraction replica transmission electron microscopy of EBSFF samples identified carbides in the 300-600 nm range, consistent with a population having the predicted maximum size. Another dispersion of carbides larger than 3 um was also observed in the EBSFF samples. These are believed to be original carbides that survived the EBSFF thermal cycle without completely dissolving. More thorough dissolution can probably be obtained with EBSFF process modifications. Control material from a conventional vacuum arc remelted ingot with similar composition was also examined and plate-like carbides up to 40 urn in length were noted. This is an indication of the enormous potential of the EBSFF process to refine the carbide morphology and size distribution without the need for a reduction in carbon content.

"Order of magnitude scaling of complex engineering problems, and its application to high productivity arc welding," P. F. Mendez, Thesis (Ph.D.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, p. 195, 1999.
Abstract: This thesis presents the Order of Magnitude Scaling methodology and uses it to determine the configuration and dominant forces in the weld pool during high productivity arc welding. This methodology was developed to consistently address problems for which experimental and mathematical treatment is difficult, yet the governing equations and some general characteristics are known. The results generated by this methodology can be grouped into two sets. One of these consists of estimations of the unknowns of the problem in the form of power laws. The other is a set of dimensionless groups that indicates the relative importance of the driving forces. It is not necessary to solve the original differential equations, because they are transformed into a significantly simpler set of algebraic equations. This transformation is possible through the combination of dimensional analysis and asymptotic considerations. A new condition is introduced for normalization: that the dimensionless functions vary smoothly. This essential condition was not considered in previous research. Matrix algebra is used to provide a systematic treatment for problems involving many parameters. The application of this technique to high productivity arc welding determined for the  first time that the dominant force acting on a very depressed weld pool is the arc drag force. Experimental work in 304 stainless steel was performed to analyze the effect of the large depression on defect formation. It was found that higher welding speeds (20% or more) are possible with lower sulfur content (6 ppm vs. 230 ppm). Differences in the size and stability of the weld pool depression are proposed here as the explanation for this di erence. Steels with lower sulfur content show a weld pool geometry that tends to decrease the size of the gouging region (the most depressed part of the weld pool). In higher sulfur steels, the gouging region tends to extend beyond the hot region of the arc. In this situation the gouging region freezes prematurely and defects such as humping or a split bead are generated.

"Impact of scale on performance and technology in process-intensive industry," J. D. Nystrom, Thesis (Sc.D.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp. 116, 1999.
Abstract: Two surveys are performed to determine production methods, competitive strategies, and scale disadvantages for a group of small manufacturing plants. Detailed comparisons of economic, operational, and development activities are presented to identify differences between industry production standards and small-scale plants. As a group, the small-scale plants had similar production costs to the standard-scale plants. The small-scale plants experienced lower average unit fixed costs as a result of lower capital investment and indirect labor expenses. The small-scale plants operated closer to their theoretical efficiency levels than the standard-scale plants. The procedure used to collect and analyze data is referred to as the direct comparison method. The direct comparison method involves conducting detailed one-to-one comparisons of production systems at the plant-level. A pattern of operational trends are reported that contribute to the economic performance of small-scale plants. The small-scale plants compensated for scale disadvantages by having greater technology independence, conserving capital, conducting internal development, and promoting process competence.

"Analysis of a manufacturing and distribution system," Christopher Chan Ogden, II, Thesis (M.B.A.)--Massachusetts Institute of Technology, Sloan School of Management; and, (S.M.)--Massachusetts Institute of Technology, Dept. of Mechanical Engineering; in conjunction with the Leaders For Manufacturing Program, supervised by Thomas W. Eagar and Duncan Simester, pp.48, 1999.

"Spheroidization of iron powders by radiative heat transfer," Rodrigo Javier Quintero de la Garza, Thesis (S.M.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering; and, (S.M.)--Massachusetts Institute of Technology, Dept. of Mechanical Engineering, supervised by Thomas W. Eagar, pp. 80, 1999.

"Logistics and inventory management for supporting the customer service function," Dean Harper, Thesis (M.B.A.)--Massachusetts Institute of Technology, Sloan School of Management; and, Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar and Lawrence Wein, pp.94, 1998.
Abstract: Companies have invested great effort in recent years to improve profitability via better inventory control methods. In some instances, this desire of management has translated into the message that 'inventory is evil'. With this in mind, many companies have embarked on inventory reduction programs, much to the dismay of many customers. Coinciding with this company initiative has been a growing body of literature and academic work that is paving the way. The vast majority of this work has targeted manufacturing operations with little attention paid to post sale product support. The Instron Corporation has joined this move towards more efficient operations having moderate success. The company has attempted, like many others, to use leading edge materials management methods such as just-in-time procurement, kanban control systems, and other lean efforts. These manufacturing initiatives have also been applied to material classified as 'service inventory* that has accumulated over the years and in some cases decades. The planning for this material, used for maintaining customer's equipment, has been grossly neglected and the results are stunning. Many regularly used items are not actively procured, while other parts that are used very infrequently have built up extremely excessive inventory, This thesis describes a model that provides a systematic and logical way of planning a service part inventory that will economically meet customer requirements, The last section of the thesis is an appendix describing a related issue regarding product design. Due to reliability and serviceability issues, a product that tests the material properties of asphalt binder was redesigned to increase modularity. The design verification process suggested that the new proposal was sound but brought the testing process itself into question, The maximum stress and strain values exhibited large variation and several possible explanations are explored.

"Cost modeling of a manufacturing process," David Medrow, Thesis (M.S.)--Massachusetts Institute of Technology, Sloan School of Management; and, Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Electrical Engineering and Computer Science, supervised by Thomas W. Eagar and Stephen C. Graves, pp.49, 1998.
Abstract: A manufacturing firm with a wide variety of products (or SKUs) faces a substantial challenge when working to reduce in-process and finished goods inventories. In order to hold less inventory, production run sizes need to be decreased and the number of changeovers must increase. As changeovers increase, production capacity is lost and more labor is spent on nonvalue- added activities. The situation is further complicated by a difficulty in determining the true capacity of a production line or a particular piece of equipment. Capacity is affected by downtime, efficiency and changeovers. In many cases, different types of changeovers can take place and each type of changeover will have a different completion time. As companies look to find the optimum inventory levels by comparing holding costs with manufacturing costs, the variations in capacity and types of changeovers make it difficult to find the true cost. Manufacturing costs can rapidly increase if overtime is needed to compensate for additional time spent on changeovers. Finally, it is difficult to effectively target capital expenditures and process improvement plans without a clear understanding of the current capacities and cost structure. This thesis examines a cost modeling program developed for Tenneco-Automotive (TA). Tenneco's Automotive business focuses on exhaust and ride control products and has two main groups of customers: original equipment manufacturers (OEM) such as General Motors and after-market customers who install or sell replacement parts. The model focuses on the aftermarket segment since it is more variable and more difficult to forecast than the OEM business. This variability in the after-market business has a substantial impact on the manufacturing cost structure. After briefly discussing the model development process, the majority of the thesis will focus on applications of the model and Tenneco's plan to use the model to improve its manufacturing operations. The model is designed to be specific to an individual plant and has been constructed in a modular format for ease of customization. Scenarios involving production levels, overtime considerations, changeover frequency, and capacity planning can be performed for an individual machine or for an entire manufacturing process, The model determines the cost associated with each scenario and allows a user to quickly make comparisons between different production plans.

"Vertical integration and the portability of skill sets in high tech industries," B. D. Siebach, Thesis (S.M.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, and, (S.M.)--Massachusetts Institute of Technology, Sloan School of Management, supervised by Thomas W. Eagar and Donald B. Rosenfield, pp. 30, 1998.

"Variation reduction in a wafer fabrication line through inspection optimization, J. W. Bean, Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, 1997, and Thesis (M.S.)--Massachusetts Institute of Technology, Sloan School of Management, supervised by Tom Eagar, Roy Welsch, pp. 52, 1997.

"Thermodynamic data from multi-component metallic diffusion couples," T. Imai, Thesis (Sc. D.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp. 291, 1997.
Abstract: One of the most important characteristics of multi-component metallic systems is the free energy interactions between the solute elements. Much research has been done to measure these values in multi-component systems, especially in iron based alloys. However, few measurements have been done successfully in reactive metal systems such as Ti and Nb alloys. This is mainly because these reactive metals interact with their container in the liquid state or even in the solid state. A new method was developed to derive the free energy interaction coefficients of multicomponent systems from diffusion profiles. While diffusion is inherently a transient phenomenon and chemical interaction is a thermodynamic property, the driving force for diffusion is based on the thermodynamic potential difference. By measuring the diffusion profile in some ternary metal systems, one obtains a discontinuous diffusion profile, the interfacial values of which can be related to the activity coefficients. Local thermodynamic equilibrium was confirmed at the interface, and the free energy interaction coefficients were successfully derived from chemical compositions at the interface.

"Developing a maintenance strategy : a case study in an automotive assembly plant," Eunmee Park, Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering,supervised by Thomas Eagar, Jan Klein,  pp.121, 1997.
Abstract: This thesis examines challenges in adopting world class maintenance practices. Specifically, it describes research conducted regarding efforts to enhance the equipment efficiencies within a mature automotive assembly plant. Although the policy deployment of other goals and objectives were considered successful, the plant's efforts to adapt some of the world class maintenance practices did not work so well. As part of the policy deployment, a preventive maintenance team was formed to improve up-times of specific equipment. This thesis explores the reasons behind the difficulties in planning and implementing change in maintenance systems. This thesis presents recommendations on developing a more effective maintenance strategy, based on the research and prevalent theory related to cultural change, project management, team formation and world class maintenance systems. It also suggests mechanisms available to leadership for cultural change and describes tools to build commitment towards a shared vision.

"Study of chromium in welding fume," P. Sreekanthan, Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp. 93, 1997.

"Applications of powder interlayers for large gap joining," Wei-Dong Zhuang, Thesis (Ph.D.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp.214, 1997.

"A framework for determining the mechanical properties of dissimilar material joints,Ó B. E. Blackwell, Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp. 142, 1996.
Abstract: An overview of the various techniques influencing the performance of dissimilar material joints is presented. Currently, there is no single analytical model capable of describing the elastic stresses arising from the interaction of two materials to a change in temperature. The applicability of continuum techniques is made difficult by the presence of singularities and the influence of geometry on mechanical loading. Numerical approaches are not immune to difficulties either. Due to the influence of singularities, peak stress metrics are very susceptible to the model formulation within finite element analysis. An alternative metric, based on strain energy, was shown to offer much higher precision while incorporating the effect of material properties, joint geometry and bonding temperature. In the past, many modeling efforts have been limited by the ability to predict and incorporate realistic mechanical properties which are valid over a wide range of temperature. Through a combination of deformation mechanism maps and dislocation mechanics, a material behavior model was developed which is sensitive to the dominant effects present in dissimilar material joints. The validity of this approach was evaluated by examining a number of case-studies and by mechanically testing copper : molybdenum dissimilar material joints fabricated by vacuum brazing.

"Evolution of the entrepreneurial firm product strategy and organizational design, ÓJ. B. Burke, Thesis (M.S.)--Massachusetts Institute of Technology, Sloan School of Management, supervised by Rebecca M. Henderson, Thomas Eagar, pp. 136, 1996.
Abstract: This thesis documents the evolution of organization, technology strategy, and product development at a rapidly growing, medium-sized firm engaged in the design, manufacture, and distribution of capital equipment to the electronics industry. It captures ideas, thought processes, and knowledge developed during a six month Leaders For Manufacturing Program internship. Perspectives in organization design, the economics of organization, models of organization, and change theory are reviewed. We apply these ideas in the context, of the firm. Experiences in engineering and manufacturing projects with the firm highlight the need for change. A tiered-team organization, supporting improved business processes, is created. Preliminary results of the change effort, including the implementation of a technology and product strategy process, are provided. Finally, we reflect on the results in light of the problems we set out to resolve and the theories that shaped our efforts. This thesis documents the application of existing ideas. It provides some insight into the problems faced by a rapidly growing, entrepreneurial firm as it transitions into a larger organization.

"Growth of intermetallic phases at low temperature," C. A. Klepser, Thesis (Sc. D.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp. 138, 1996.

"Organizational learning in a platform team environment and the development of hard-top doors," C. D. Oates, Thesis (S.M.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering; and, Thesis (S.M.)--Massachusetts Institute of Technology, Sloan School of Management, supervised by Thomas W. Eagar and James M. Utterback pp. 98, 1996.

"The influence of cooling rate on the microstructure of metal alloys," D. A. Penta. Thesis (B.S.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp. 30, 1996.

"Methodology for the synchronization of material flow in an assembly plant," M. A. Polizzi, Thesis (M.S.)--Massachusetts Institute of Technology, Sloan School of Management, 1996, and Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Mechanical Engineering, Thomas W. Eagar and Donald B. Rosenfield, pp. 60, 1996.

"A constraint based optimization of manufacturing and sales in the copper tubing industry," J. M. Strimling, Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Mechanical Engineering, 1996, and Thesis (M.S.)--Massachusetts Institute of Technology, Sloan School of Management, supervised by Thomas W. Eagar, Vien Nguyen, pp. 82, 1996.

"Dynamic electrode forces in gas metal arc welding," Lawrence Anthony Jones, Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Jeffrey H. Lang and Thomas W. Eagar, 1996.
Abstract: In gas metal arc welding, a low-voltage electric-arc plasma is maintained between a work-piece and a wire electrode, both of which are melted by the arc. This thesis examines the dynamic forces that affect the detachment of molten metal drops from the consumable wire electrode. Unlike drops falling from a water faucet, the drops in gas metal arc welding experience strong magnetic forces generated by the interaction of the welding current with its own magnetic field. An extensive set of clear high-speed motion images of metal drops detaching from a welding electrode was collected under a wide variety of conditions. The images are used to measure the surface tension of steel as it is found in a gas metal arc welding plasma. Impulse-response oscillations of pendent molten steel drops are also measured. A derivation of the magnetic forces acting on necking drops is performed. Numerical computations of these forces are performed by using shapes fitted to high-speed images of molten steel drops as they are ejected from the electrode by magnetic forces during short-duty-cycle current pulsing. A dynamic model of drop detachment is developed and used to study the competition between the retaining surface tension force and othei forces (magnetic, gravitational, and inertial). Simulations performed with this model are compared with extensive measurements of constant-current welding images and with limited measurements of pulsedcurrent welding images. The comparisons indicate that the experimental magnetic forces are much less potent than the calculated magnetic forces when welding-current transients are not present. A hypothesis is advanced that internal flows are able to develop under the relatively quiescent conditions that exist during drop development in constant-current welding. An apparatus was constructed to axially vibrate the electrode as it is consumed. Experiments using inertial forces to induce drop detachment are shown. Comparisons of experimental measurements with simulations performed with the dynamic drop-detachment model indicate results similar to pulsed-current welding, namely that magnetic forces are more effective under non-quiescent conditions, regardless of whether the disturbances are magnetic or mechanical in origin.

"Options analysis--an innovative tool for manufacturing decision-making," Craig Spencer Belnap, Thesis (M.S.)--Massachusetts Institute of Technology, Sloan School of Management, 1995, and Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Materials Science & Engineering, supervised by Thomas W. Eagar, James M. Utterback, pp.123, 1995.

"Process improvements in laser diode manufacturing : identifying variation and the economics of reducing it," Mark Soterios Coggin., Thesis (M.S.)--Massachusetts Institute of Technology, Sloan School of Management, 1995, and Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Materials Science & Engineering, supervised by Thomas W. Eagar, Vien Nguyen, pp. 181, 1995.
Abstract: Several analyses were undertaken in an effort to determine how and where variation in the performance of laser diodes originated. The analyses consisted of quantifying the variation that existed in the performance of the diodes' threshold current, establishing correlation between variations in threshold current and other attributes of the laser diode, and conducting experiments to determine causes of the variation. Linear and multivariate regression results indicated that the threshold current performance of the laser diodes was positively correlated to facet reflectivity. This supports previous theoretical models of the laser diode. The analyses also indicated that variability in threshold current did not adversely affect laser reliability. Further experiments showed that the laser diode test equipment, spatial variation in the wafer, and the bar cleaving process did not contribute to the variation in threshold current. Analyses of the facet coating process showed mixed results, indicating that although the coating thickness was uniform, other attributes of the coating such as stoichiometry may have caused variations in threshold current. A cost model was also constructed for a hypothetical manufacturing process. The results showed that the economics of improving a manufacturing process dictate that total costs will not always be minimized at higher production yields. This holds true especially if the costs of improving the processes are high. The results regarding the economics of process improvement are presented as a series of frameworks and strategic factors.

"Electron beam (EB)-assisted materials fabrication," Vivek Ramesh Dave, Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp.280, 1995.
Abstract: The principal contributions of this work to the field of electron beam materials processing are fourfold. 1) Electron beam - based materials fabrication was demonstrated using a wire feed technique. The experiments demonstrated the successful deposition of 308 stainless steel onto a 304L stainless base. Crack-free deposits in excess of 1.25 cm thickness were deposited. Layered structures consisting of Al-Bronze deposits on a Monel 400 base were also made. These experiments demonstrate the feasibility of EB-based SFF (Solid Freeform Fabrication). 2) A new pressureless technique for the EB-assisted reaction synthesis of aluminide interrnetallics was developed. This technique allows control over the position of the reaction front and results in full density and full extent of reaction for such systems as FeAl and Fe3Al. The technique was successfully applied to the deposition of fully dense and adherent coatings on steel. 3) Several materials processing applications were implemented using high energy electron beams (HEEBs). These include shock surface strengthening, ceramic strengthening, and C/C joining. The potential benefits of HEEB shock processing in SFF (Solid Freeform Fabrication) are discussed. This present work represents one of the most extensive surveys of the applicability of HEEBs to materials processing in existence. 4) A thermal model was developed to describe the temperature profiles due to moving distributed volumetric sources. This model takes into account the volumetric penetration effects of electron beams and extends existing models for distributed surface sources. The model is applied to several processing applications and is compared to actual ebeam operating parameters.

"Selection of operations management methodologies in disparate cost environments," Mark Richard Kurz, Thesis (M.S.)--Massachusetts Institute of Technology, Sloan School of Management, and Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Mechanical Engineering, supervised by Thomas W. Eagar, Donald B. Rosenfield, pp. 86, 1995.
Abstract: Managers are deluged with a steady stream of operational techniques by academics, consultants, and the business press. These techniques are merely business tools, but questions can arise. How does an operations manager choose from the wide variety of tools? Which tool is most appropriate? This thesis explores these questions in detail by quantitatively evaluating the strategies of Six Sigma, Theory of Constraints, The Inventory Solution, and Just-In Time (JIT). The objective of this thesis is to substantiate the hypothesis that the appropriate operational strategy depends largely on the cost environment of the business. No single operational strategy is universally superior. The motivation for this work stemmed from a fundamental conflict in operational philosophies for an assembly area at a US manufacturing plant. At the time of this work, industrial engineering management was considering two distinct operations approaches: the continuation of a traditional balanced line method, or the intentional switch to a Theory of Constraints approach. The conflicting messages of these two techniques around capacity allocation triggered this study. After reviewing the theories of the four operations strategies mentioned above, this study uses results from simulation studies to support the hypothesis that no single operational strategy is universally superior. Several experimental cases are presented to show that the cost environment of a business will largely influence the choice of operations strategy. As such, the significance of the organization's cost accounting system will become quite apparent. The simulation results provide quantitative support for deciding which operational technique to adopt. Using both simulation results and organizational analysis of the assembly operations, this thesis also discusses the benefits of coordination and synchronization in processes. The behavior that comprises teamwork requires some investment, but can also generate worthwhile returns. This thesis applies the results of both the fundamental study on operations management techniques and the discussion of teamwork to the assembly operations at a US manufacturing company. Finally, while the operational theories are useful in describing many systems, this thesis also addresses the shortcoming of observing problems solely from one framework. Specific problems will often require tailor-made solutions. This thesis substantiates that no single operations theory is universally superior. The appropriate method for success depends largely on the cost environment of the business. Astute managers recognize the appropriate business tool for their situation and allocate resources accordingly.

"Surface layer formation on Pb/Sn alloys," C. S. Lee, Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar., pp. 80, 1995.
Abstract: With recent advances in silicon technology, microprocessor performance is becoming limited by chip-to-package interconnections. Three primary assembly processes, Wirehonding (WB), Tape Automated Bonding (TAB) and Controlled Collapsed Chip Connection (C4), are used. Out of the three assembly processes, this study focuses on C4 technology where a chip is interconnected to a package by a matrix of solder bumps. C4 offers many advantages over WB or TAB, such as a high input/output density and better overall electrical performance. Pb/Sn bumps are used as connectors in the C4 technology. Pb/Sn solder bumps produced by electroplating were extensively studied. The use of Pb/Sn electroplating process for C4 requires the ability to etch Ball Limiting Metallurgy (BLM) in the presence of Pb/Sn bumps. Therefore, the appropriate etchant needs to be selected. Upon etching, a surface corrosion layer is formed and an appropriate cleaning acid needs to be selected to remove this layer subsequently. This thesis examines surface layer formation on solder bumps, the morphology of the surface layer and surface layer composition. It was found that the morphology of the surface layer formed on the Pb/Sn Solder bumps is critically dependent on the concentration of the etchant, especially H2SO4. Using a gravimetric test, XPS and AES analysis, PbO containing Sn and S, was identified to be the primary component of the surface layer after the BLM etch. Moreover, the impact of the BLM etch bath on Pb/Sn solder bumps was investigated. The thickness morphology, composition and the growth rate of the layer are critically dependent on S from H2SO4. In H202-rich solution, the surface appears to be loosely packed and the growth rate on the surface of the bump was found to be reaction-rate limited; whereas, in H2S04-rich solution, the diffusion rate is the controlling step in forming the surface layer on the solder bumps. Also, the layer was thin and dense. Moreover, from the AES scan and the concentration variation of the BLM etch studies, the optimal concentration was determined to be 86% H2SO4 solution which results in very slow surface layer growth, limited by the diffusion rate. Using that concentration, BLM etch rates in vertical and lateral directions were studied. The overall etch rate in the lateral direction was determined to be 3 um.min; whereas, the vertical etch rate was about 1.5 um/min, thus the etch rate is anisotropic. Further research needs to be focused on the BLM etch rate studies and on developing better methods for measuring thickness and solubility.

"A manufacturing cell design tool for the development and evaluation of transfer lines," Scott L. Ransley, Thesis (M.S.)--Massachusetts Institute of Technology, Sloan School of Management, and Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Mechanical Engineering, supervised by Thomas W. Eagar, James M. Utterback pp. 100, 1995. Thesis Supervisor .

"Representing troubleshooting information for a high-volume production line," C. M. Brennan, Thesis (M.S.)--Massachusetts Institute of Technology, Sloan School of Management, 1994, and Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Electrical Engineering and Computer Science, supervised by Alvin W. Drake, Thomas W. Eagar, Donald Rosenfield, pp. 75, 1994.

"Application of cellular manufacturing to low-volume industries," Paul W. Dul, Thesis (M.S.)--Massachusetts Institute of Technology, Sloan School of Management, 1994, and Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Materials Science & Engineering, supervised by Thomas W. Eagar., pp. 65, 1994.
Abstract: Traditionally, aerospace and other low-volume manufacturers have structured their operations around process center layouts. This layout was adopted to cope with the high product mix and low-volumes with which these companies were faced. Product layouts, with their high levels of capital investment, were not adopted by low-volume manufacturers due to their high contribution to unit cost. The key to achieving a product layout lies in generating sufficient volume over which to distribute capital costs. Two approaches can be taken to increase volume: (1) design parts such that they are substantially similar and (2) design manufacturing systems such that they are flexible enough to produce a wide variety of parts while incurring little to no set-up time between parts. These two approaches allow economies of scale and scope to be generated even in low-volume industries. This thesis presents a case study undertaken at the Boeing Commercial Airplane Group's Renton Division. It shows how cellular manufacturing can be applied to low-volume products for substantial gain. The study focuses on the production of doors for the 737 and 757 aircraft in Renton's Door Responsibility Center (DRC). It projects that cost savings in excess of 50% are achievable via cellular manufacturing. It also contends that cellular manufacturing can be extended across detail part fabrication to attain significant cost reductions throughout Boeing's product line. While the study points to specific cost reductions, most of which are precipitated by decreases in labor expense, it also stresses that their are many less easily quantifiable gains to be made via cellular manufacturing. These must also be considered when evaluating the merit of cellular manufacturing projects.

"An automotive lower back seat system design," William Giacomo Fonte, Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp. 90, 1994.
Abstract: The goal of this work was to study the effect of different materials used in lower back support systems in automotive seats. The recyclability of materials used in seat cushions is presented as well along with the optimization of their design for assembly as well as disassembly.. Gaining the understanding needed to move forward required substantial investigative learning up front. The primary vehicles for this were (1) literature searches, (2) conversing with experts (academic and otherwise) at the forefront of research and design in the area of seat development, and (3) contact with existing users of automotive seats. Although some of the concepts considered were novel, the final concepts represent ideas more in the mainstream of current seat design practices. One design (the CushAire lumbar support system) is presented in this report. The CushAire design consists of an orthopedically shaped inflatable/deflatable composite foam cushion which, when actuated by the user by depressing a single button, vents air through a single valve allowing the cushion to take the shape of the individual's lumbar region while providing uniform support. The design philosophy here was to combine a device which is capable of providing physiologically correct support with a second device which can distribute this support dependent upon body type and customer preference. The CushAire design relies upon a composite foam structure to provide physically-correct support that is compliant enough to match different body types. The front layer of foam in the inflatable/deflatable cushion provides compliance dependent upon body type and individual preference while the rear cushion provides support for the lumbar region.

"A de-proliferation methodology for the automotive industry," William Giacomo Fonte, Thesis (M.S.)--Massachusetts Institute of Technology, Sloan School of Management, 1994, and Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Mechanical Engineering, Thomas W. Eagar, Karl T. Ulrich, pp, 49, 1994.
Abstract: General Motors North American Truck Platforms (NATP) has identified the need to reduce product complexity through product de-proliferation as a strategic means to produce higher quality products at lower cost. This thesis presents a de-proliferation methodology based on perceived customer values and the impact of product features on organizational performance. The study addresses both short- and long-term de-proliferation. In the short term, the focus is on eliminating dysfunctional variety (i.e., that perceived by the customer as valueless). The long-term objective is to offer product options that meet customers' desired level of variety but have a low impact on organizational complexity, thereby maximizing profits. A case study of a representative de-proliferation of rear axles on full-size pickup trucks is used to illustrate the process delineated by this presentation. The rear axle de-proliferation effort at North American Truck Platforms eliminated 67 of 131 axles. The projected lifecycle savings of de-proliferating rear axles was estimated to be $82 million. This study offers a process for extending the de-proliferation of rear axles to all truck components.

"Pilot process development for a medical diagnostic product," L. Kimball-Zwetchkenbaum, Thesis (M.S.)--Massachusetts Institute of Technology, Sloan School of Management, 1994, and Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Mechanical Engineering, Donald B. Rosenfield, Thomas W. Eagar, pp.80, 1994.

"The cost of variation and a process to reduce variation in the assembly of mature aircraft designs," Rhonda L. Reynolds, Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Mechanical Engineering, 1994, and Thesis (M.S.)--Massachusetts Institute of Technology, Sloan School of Management, supervised by Thomas W. Eagar, Karl T. Ulrich, pp. 55, 1994.
Abstract: The quality and the price of a product are two of the main sources of competitive advantage. These in turn are very dependent upon the production processes used to produce the product. Variation in the production process is a major source of waste, rework, non-value-added costs, and lowered quality. The Boeing Company is the world's leading manufacturer of Commercial jet aircraft. However, this industry is fiercely competitive, and Boeing will not be able to rest upon its past laurels. As the cornerstone of Boeing's strategy to maintain its premier position, the company has committed itself to the continuous improvement of its products and processes. Reducing and controlling variation in the production process would greatly contribute to Boeing's goal of cutting waste. lowering costs, and boosting quality. This thesis documents the author's findings as a result of a six month internship at The Boeing Company in the Door Responsibility Center. The following are provided: * A discussion of the effects of variation on production costs and product quality * A discussion of Boeing's process to reduce and manage variation on new designs through the use of key characteristics, as well as the limitations of applying this process to older designs * An estimate of the costs of variation based on a case study of shimming and trimming the 757 # 4 Passenger Door * A proposed method for reducing and controlling variation in the assembly of mature products Variation in the production process results in rework, which currently accounts for approximately 40% of the direct labor to build an airplane. In the Door Responsibility Center, the estimated annual cost of shimming and trimming alone is $1.19 million, and these operations account for only a small portion of the rework resulting from variation in the parts and the assembly process. The use of key characteristics alone will not solve the variation related production problems. To correct these problems, an in-depth investigation of the design, the detail parts and assemblies as-produced, the manufacturing plan, and the tool indexing plan is required in addition to the identification and measurement of key characteristics.

"The cause of cellular solidification structure during transient liquid bonding," Dalero W. Berkeley, Thesis (B.S.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp.50, 1993.

"Designing measurement systems in a manufacturing environment," Michael J. Blatz, Thesis (M.S.)--Massachusetts Institute of Technology, Sloan School of Management, 1993 and Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Mechanical Engineering, supervised by Thomas W. Eagar, pp. 61, 1993.
Abstract: In the increasingly complex world of manufacturing, the ability for an organization's leader to understand and control the systems by which an organization functions is becoming a prerequisite for success. In addition to setting a vision, building this vision into a shared commitment and providing the resources necessary to accomplish appropriate objectives, the leader must assume this role of designer of the structures by which the organization functions Such systems may provide structure for capital budgeting decisions, evaluation and promotion, market evaluations, or even employee suggestion programs. Systems are the structure by which we operate. Failure to recognize, understand and control these structures will bequeath them to chance. The goal of this thesis project was to demonstrate that a large corporation could benefit from a closer partnership between two internal divisions. One of these divisions functions as a fabricator and supplier to the other, a Line of Business involved in office equipment manufacturing. The existing relationship between these two internal organizations is strained and uncooperative Management's original intention was to show that a closer relationship could reap benefits for the company Consequently, demonstrated benefits would result in the impetus for further partnering An approach of this manner fails to address the underlying structure or "system" that is truly causing Ae problem. This thesis examines the systemic impact of the company's measurement system on the aforementioned relationship. It demonstrates how the metrics that management uses to evaluate the performance of three major constituencies inhibits productivity improvements, places little value on engineering partnerships and costs the company millions of dollars through poor purchasing decisions. This paper highlights the underlying structure and proposes a method for creating a new measurement system that is consistent and supportive of management's objectives.

"Identifying and reducing the major components of lead-time in an electronics manufacturing facility," Chad Jensen Clawson, Thesis (M.S.)--Massachusetts Institute of Technology, Sloan School of Management, 1993 and Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Electrical Engineering and Computer Science, supervised by Thomas W. Eagar and Charles H. Fine, pp. 135, 1993.

"Shock hardening of 5052 and 6061 aluminum by a high energy electron beam," Mohammad Farnush, Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Kennth C. Russell and Thomas W. Eagar, pp. 63, 1993.

"Influence of shielding gas composition on alloy recovery during gas metal arc welding," Heidi Gibson, Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp.50, 1993.

"Process monitoring methodologies for sheet metal assembly operations," Gregory Alan James, Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Mechanical Engineering, Thomas W. Eagar and James M. Utterback, pp. 137, 1993.

"A systematic approach and framework for optimizing a polymer sheet manufacturing operation," Jonell Kerkhoff, Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, 1993, and Thesis (M.S.)--Massachusetts Institute of Technology, Sloan School of Management, supervised by Tom Eagar and James Utterbac, pp. 106, 1993.

"Hydrogen degradation of high strength steel weldments," Christos Konstantarakis, Thesis (Ocean. E.)--Massachusetts Institute of Technology, Dept. of Ocean Engineering, 1993, and Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Materials Science & Engineering, supervised by Thomas W. Eagar and Koichi Masubuchi pp. 43, 1993.

"Measuring customer-driven manufacturing process improvement in a multidivisional corporation," Jonathan A. Rennert, Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Mechanical Engineering, supervised by Thomas W. Eagar and Stephen C. Graves, pp. 58, 1993.

"Design of a process development model focusing on key decision factors for pre-project planning," Mary Ann Robinson, Thesis (M.S.)--Massachusetts Institute of Technology, Sloan School of Management, supervised by James J. Utterback and Thomas W. Eagar, pp.84, 1993.

"Feasibility of low-temperature transient liquid phase bonding of TI-6AL-4V alloy," Karl C. Scholoer, Thesis (B.S.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp. 38, 1993.

"Scheduling employees of a manufacturing facility," David J. Seitelman, Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Mechanical Engineering, supervised by Thomas W. Eagar and Stephen C. Graves, pp.68, 1993.

"Cost and quality drivers in printed circuit board assembly," Elizabeth Jane Altman, Thesis (M.S.)--Massachusetts Institute of Technology, Sloan School of Management, 1992 and (M.S.)--Massachusetts Institute of Technology, Dept. of Mechanical Engineering, Thomas W. Eagar and Charles H. Fine, pp.67, 1992.

"Building core competencies in auto body panel stamping through computer simulation," Tracy Lynn Harrison, Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, 1992 and Thesis (M.S.)--Sloan School of Management, supervised by Thomas W. Eagar and James M. Utterback, pp.95, 1992.

"Low temperature transient liquid phase bonding for electronic packaging," Michelle M. Hou, Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp.50, 1992.

"Precision laser micromachining of ceramics," Luciano Spiridigliozzi, Thesis (M.S.)--Massachusetts Institute of Technology, Sloan School of Management and (M.S.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar and Stephen C. Graves, pp.50, 1992.

"Analysis of residual stresses in ceramic/metal braze joints using finite element methods," Charles Bradley Sweeney, Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp.91, 1992.

"Prototyping--paths to the present," Stephen Hom, Thesis (Mech. E.)--Massachusetts Institute of Technology, Dept. of Mechanical Engineering, supervised by Thomas W. Eagar and Stephen C. Graves, pp.126, 1991.

"Joining of 6061 aluminum matrix-ceramic particle reinforced composites," Russell Klehn, Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp.77, 1991.

"Improving the strategic contribution of new technology--learning from a sheet metal FMS," James C. Leonard, Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of MEchanical Engineering, and Sloan School of Management, supervised by Rebecca Henderson and Thomas W. Eagar, pp.186, 1991.

"The development and implementation of an improved measuring methodology for aluminum plate," Julia Christine Putnam, Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, and Massachusetts Institute of Technology, Sloan School of Management, supervised by Stuart B. Brown, Thomas W. Eagar, Thomas A. Kochan, pp. 170, 1991.

"Designing a technology policy for innovation in flat panel displays : overcoming ideology, uncertainty, and imperfect information to achieve economic growth," Joseph Anthony Raguso, Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas Eagar, pp. 174, 1991.

"An investigation of low temperature transient liquid phase bonding of silver, gold, and copper," John W. Roman, Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp.112, 1991.
Abstract: Low temperature transient liquid phase bonding is a process where metallic bonds are made by soldering at a temperature of less than 165OC and then holding at that temperature for a specified time. This process involves the dissolution of the base metals, silver, gold or copper, into the joining alloy and solidification at the joining temperature. These bonds can be made resistant to remelting temperatures much higher than the original bonding temperature. Since these bonds are formed at low temperatures the stress developed from differential expansion is minimized. The work reported in this thesis involved investigation of combinations of the three base metals with each of fifteen solder alloys or elements. The remelting temperature of bonds produced was determined. Indications of low temperature transient liquid phase bonding were evident in the majority of these combinations. Shear strength testing of selected bonds was performed to measure the strength relative to conventional solder bonds. Low temperature transient liquid phase bonding may be applicable to the mounting of temperature or stress sensitive electronic components.

"Use of the design structure matrix in the improvement of an automobile development process," Michele W. Sequeira, Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, and Massachusetts Institute of Technology, Sloan School of Management, supervised by Thomas W. Eagar, James Utterback, Steven D. Eppinger, pp.68, 1991.
Abstract: Improving the efficiency of a process has gained considerable attention, especially in the automobile industry. While efficiency improvement may be approached from either a task orientation in which the individual tasks are made more efficient, or from a systems orientation in which the interrelationships between tasks are improved, most analysis tools and their solutions are task oriented. The Design Structure Matrix, in contrast, takes a systems orientation, allowing the entire system to be considered. It shows, in compact notation, the interrelationships between tasks. Marks placed in specific places in the matrix show, for each task, from which tasks inputs are received and which tasks information is supplied to: In addition, feedback loops which play a significant role in most processes, are clearly identified through the use of the matrix. Controlling the communication between the tasks in a feedback loop is vital to the timely and accurate execution of the process. This analytical tool was applied to the automobile development process, with concentrated emphasis on the first half of the process. From this analysis several major feedback loops were identified; two major loops constituted the first half of the process. Based upon the matrix and knowledge of the development process, several options for improvement were formulated. The changes to the system vary from the most radical option of changing process milestones to simpler changes to individual tasks. In addition, the tool itself was introduced to the sponsoring company for its application to subprocesses.

"Impact of manufacturing process and task designs on work team performance," Augustus Own Tai, Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, and Sloan School of Management, supervised by Thomas Kochan, Thomas W. Eagar, pp.80, 1991.

"Correlations between resistance spot weldability and thermal contact conductance," Cesar M. Calva, Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp.80, 1990.

"Issues in new product development--the introduction of tape automated bonding technology," Virginia Loop Maggs, Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Mechanical Engineering, supervised by Thomas Eagar and Charles Fine, pp.180, 1990.

"Tape automated bonding--product and process ramp-up," Benjamin R. Samuels, Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, 1990, and Thesis (M.S.)--Massachusetts Institute of Technology, Sloan School of Management, supervised by Thomas Eagar and Marcie J. Tyre, pp. 133, 1990.
Abstract: Tape automated bonding (TAB) is currently the fastest-growing electronic packaging technology. It offers significant lead density advantages over conventional wirebonding and significant heat dissipation advantages over flip-chip techniques, Motorola, Inc. and Digital Equipment Corporation selected advanced TAB for the Motorola chip which drives Digital's new entry into the high-performance computer market. The materials technologies involved in the TAB development efforts are leading edge. This thesis details some of the research performed in support of process development efforts at Motorola's TAB facility. It characterizes yield variation at Motorola and traces it to specific steps in a vendor's TAB tape manufacturing process. Motorola and Digital are involved in multiple product and process rampups in support of Digital's computer. Management literature is beginning to recognize that the metrics for success in ramp-ups are sometimes very different from those of a mature technology. Companies which compete in products with very short life cycles must learn to manage the problem solving process in environments characterized by high pressure and uncertainty. This thesis discusses problem solving under those conditions as i t was observed at Motorola in their TAB ramp-up. It presents new insights into the applicability of traditional cognitive models of problem solving and offers specific suggestions for improving the problem solving environment in the Motorola ramp-up.

"Thermodynamic data from diffusion couples," Rakesh Rameshchandra Kapoor, Thesis (Sc. D.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp.197. 1989.
Abstract: The goal of this investigation was to use the information available from a binary metallic diffusion couple to compute the solution thermodynamics (activity composition relationship) for isomorphous binary metallic systems. Using a linearly constrained, notlinear least squares based algorithm that was developed during this investigation, it is now possible to compute the entire activity - composition curve for isomorphons binary metallic systems given only the interdiffusion coefficient as a function of composition (D - c data), and one additional piece of information such as the measured activity at ONE particular composition or the slope of the Henry's law line at infinite dilution. The Inherent non uniqueness of the problem leads to multiple solutions on an activity-composition diagram. The single additional piece of information (the measured activity at one composition or the Henry's law line) is used in selecting the correct solution from the set of possible solutions, The algorlthm was applied to ten isomorphous binary metallic systems for which data on the chemlcal interdiffusion coefficient as a function of composition was obtained from the literature, For eight out of the ten systems the algorithm located a solution that either matched the experimental data reported In the literature or exhibited a trend very similar to it. There is no experimental data for one additional system and for another system the predicted activities did not match the measured activities. The algorithm may be easily extended to systems containing a miscibility gap. The algorithm represents a new technique for obtaining thermodynamic data from a source that has previously never been used to generate thermodynamic information, namely a diffusion couple. It should be particularly useful for reactive and refractory metal systems for which there is currently a paucity of thermodynamic data caused by experimental difficulties. It will also check the consistency between the available data on interdiffusion coefficients and the activity data.

"Analyses of resistance spot welding lobe curve," Euiwhan Kim, Thesis (Sc. D.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp. 301, 1989.

"Metal transfer in gas metal arc welding," Yong-Seog Kim, Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp. 294, 1989.
Abstract: This investigation explores the effects of welding parameters on metal transfer phenomena in Gas Metal Arc Welding (GMAW). The welding parameters studied include welding current, shielding gas composition, welding material, and electrode extension. Droplet sizes were measured for steel, aluminium, and titanium electrodes by high speed videography and compared with predicted droplet sizes predicted by the static force balance theory and the pinch instability theory. The comparison shows that the droplet size predicted from the static force balance theory can predict the droplet size reasonably well in the range of globular transfer, but deviates significantly in the range of spray transfer. The cause of the deviation was found to be due to tapering of the electrode tip during welding. Heat transfer mechanisms in the electrode were studied in order to couple metal transfer with heat transfer. Electrode melting rates were measured as a function of the welding parameters and fitted into the qudratic function proposed by previous investigators. The coefficients of the quadratic function were compared with coefficients calculated from energy conservation theory to evaluate the validity of this theory for modeling electrode melting. It is found that the previously proposed theory is inadequate to explain electrodc melting behavior. Using a more complete temperature distribution model of the electrode, a new energy balance analysis was developed. This new model included: joule heat, condensation heat, and heat input through the liquid-solid interface. The rate controlling step for heat transfer through the liquid-solid interface was found to be conduction transfer at the interface. based on this energy balance analysis, a new model of electrode melting was proposed, which agrees witht the experimentally measured melthing rates. Combining the resuts of the droplet size prediction from the static force balance theory and the electrode melting rate measurements, a new theory of pulsed current GMAW is proposed. A theoretical pulsing frequency is predicted by this new theory. For given pulse parameters, experimental results show that there is a range of optimum pulsing freqquency and that this optimum pulsing frequency can be predicted using the theoretical pulsing frequency and natural drop transfer frequency. The pulsing parameters were also varied to investigate the effect of tapering of the electrode on the droplet size in pulsed current welding. The results are used to prove the validity of the static force balance theory in modeling the droplet size in pulsed current GMAW.

"Submerged arc welding consumables for HSLA-100 steel," Daniel Joseph Peters, Thesis (Nav. E.)--Massachusetts Institute of Technology, Dept. of Ocean Engineering, 1989 and Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Electrical Engineering and Computer Science, supervised by Thomas W. Eagar, pp.122, 1989.

"The effect of nitrogen and titanium on the toughness of high strength saw weld deposits," Stephen W. Stanko, Thesis (Nav. E.)--Massachusetts Institute of Technology, Dept. of Ocean Engineering, 1989 and Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp. 158, 1989.

"Gas-metal arc welding in pure argon," Stephen Theodore Eickhoff, Thesis. (M.S.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp. 130, 1988.

"The influence of cooling rate on the microstructure of stainless steel alloys," John Walter Elmer, Thesis (Sc. D.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp. 388, 1988.
Abstract: The emergence of high energy density welding, laser surface modification and rapid solidification as commonly used metallurgical processing techniques has greatly increased the range of cooling rates that can be accessed during the solidification of metals and alloys. The microstructures which develop during these rapid cooling conditions may be significantly different from those which develop during low cooling rate conditions as the result of access to new metastable phases with the additional kinetic limitations that accompany rapid solidification. This investigation explores the influence of cooling rate on a series of seven ternary alloys which span the line of two-fold saturation in the Fe-Ni-Cr system. High speed electron beam surface melting was used to resolidify these alloys at scan speeds up to 5 m/s. The resulting cooling rates were estimated from dendrite arm spacing measurements and were confirmed by heat flow modeling to vary from 7x100 åÁC/ to 8x106 oC/s. The microstructures that developed from each solidification condition were examined using optical metallography, electron microprobe analysis, scanning electron microscopy and a vibrating sample magnetometer. These results were used to create diagrams to predict the primary mcde of solidification, the ferrite content and the complex microstructural morphologies which develop as a function of interface velocity and composition. Changes in the primary mode of solidification with increasing cooling rate were observed in alloys that lie close to the line of two-fold saturation. The thermodynamics and kinetics of solidification were used to explain these changes by showing how epitaxially grown metastable phases can dominate solidification at high cooling rates, without the necessity of postulating the nucleation of metastable phases within the melt. The influence of cooling rate on interface stability and solidification segregation was evaluated by calculating the solutal diffusional characteristics at the tip of columnar dendrites growing under steady state conditions. These calculations were used to predict the dendrite tip undercooling for e-ch solidification condition and the results were used to evaluate the influence of cooling rate on the amount of second phase formation, the ferrite content, and the absence of second phases at high cooling rates. The solid state transformation of ferrite during the cooling of the resolidified Fe-Ni-Cr alloys was shown to be analogous to the decomposition of austenite in Fe-C alloys. Parallels were drawn between these two systems which allowed a wealth of analysis performed on the Fe-C system to be applied to the Fe-Ni-Cr system. The influence of cooling rate on the nucleation and growth kinetics of austenite was then used to explain the conditions which are responsible for the formation of grain boundary allotriomorphs, Widmanstatten platelets, Widmanstatten needles and massive austenite grains in the resolidified electron beam melts.

"Non-destructive techniques for inspection of arc spot welds," Karen Tweed Hays, Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Ocean Engineering, 1988, and Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp. 266, 1988.

"Non-contact temperature measurement," Mansoor Ali Khan, Thesis (Sc. D.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp. 100, 1988.

"Welding flux binders produced by sol-gel processing," Jon David Kryscnski, Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp.81, 1988.

"Non-uniform current distribution in spot welding," Randy Joel Bowers, Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp. 70, 1987.

"Hydrogen assisted cracking of high strength steel welds," Steven Anthony Gedeon, Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp. 361, 1987.
Abstract: Material and process parameters which affect the lobe width of galvanized steel sheet have been evaluated. Mechanisms of weld nugget formation have a l s o been investigated with the aid of dynamic inspection monitoring of the resistance and displacement. It has been found that hot-dipped galvanized coatings have a wider range of acceptable welding conditions than the commercial galvannealed products, due to the Fe-Zn intermetallic morphology and coating composition. Small variations in thickness of the hot-dipped coatings seem to have a minimal effect on the welding range. Surface roughness was shown to have no effect on lobe width. Upsloping and downsloping of the weld current increases the welding range of hot-dipped products when using truncated cone electrodes, whereas sloped current has shown no advantage for the galvannealed or uncoated materials. Radiused electrodes can increase the lobe width of hot-dipped products but are not beneficial when using sloped current or when welding galvannealed or uncoated materials. Preheating seems to have the same effect on lobe width as upsloping. Dynamic inspection monitoring can be useful for understanding and following the progression of weld nugget formation, but has not been entirely satisfactory to date for quality control monitoring.

"Brazing alloys for ceramic to metal joining," Rakesh R. Kapoor, Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp.208, 1987.
Abstract: The poor flow of conventional brazing alloys on ceramic materials necessitates addition of reactive metals that promote flow by decomposing a thin surface layer of the ceramic. The design philosophy behind such alloys is presented here. Several experimental alloys were prepared by arc melting under a protective argon atmosphere. These were tested for wettability on Si N at 9 5 0 ~ . The contact angle setup used was fabricated during this investigation. Some of the wetted samples were sliced and examined metallographically using optical microscopy, scanning electron microscopy and electron microprobe techniques. The results indicate that reactive metal additions of Ti and Zr to conventional brazing alloys promote flow over Si N . Of the two, Ti is the 3 more potent reactive metal. Alloys that flowed well (contact angle less than 15') were: (i) Cu-80%,Sn-10%,Ti-10% (ii) Cu-70%,Sn-20%,Ti-10% (iii) Ag-Cu eutectic + 5% Ti (iv) Ag-Cu eutectic + 5%Zr. Of these, the first three had been reported by earlier investigators while the fourth is a novel brazing alloy, No conclusive correlation was found between the thickness of the intermetallic layer and the wetting behavior,

"Slag detachability from submerged arc welds," Adebisi Oladimeji Oladipupo, Thesis (Sc. D.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, p. 206, 1987.
Abstract: Over fifty percent (50%) of the total steel weld metal is deposited by one of the flux-shielded processes. Slag adherence to the weld metal surface is one of the major factors controlling the usefulness of these processes. Slag attachment to the weld metal, especially in a multipass welding, can severely degrade the weld metal properties. Hence, any improvement in the welding flux technology that eases slag detachability will be applicable to both a wide range of industries and a wide range of welding processes. Some fluxes provide slags of poor detachability with certain electrodes and/or base metal while the same fluxes provide slags of easy detachability with other electrode-base metal combinations. On the other hand, changing of the process parameters (e.g. cooling rate) alone has been observed to affect detachability. In the cases of adherent slags, what are the mechanisms of adherence? In order to understand the mechanics of this adherence and identify the major factors affecting detachability, the physiochemical properties of the flux, electrode and base plates were studied . Chromium, and chromium oxide were found to affect the detachability of welding slags. Several welds were made with stainless steel electrodes (26.27 wt%Cr), chromium oxide-rich flux and some deposited with mild steel electrodes (no chromium) on chromium-containing base metals. Examination of the weld metal surfaces, after the slag had been detached, by scanning electron microscopy showed the presence of faceted slag particles of high melting temperature which formed during slag-metal reaction and attached in the solidifying weld metal. X-ray diffraction analyses showed these particles to be chromium spinels (iron chromate, magnesium-aluminumm chromate). These particles have a melting temperature in excess of 1600 C. On the other hand, titanium oxide's detrimental effect on slag detachability was due to the formation of high melting temperature (> 1900 C) perovskites (calcium titanate) that also attach to the solidifying weld metal. The irregular interfaces formed by these solid reaction products then provide regions into which the molten slag solidifies and mechanically interlocks resulting in poor slag detachability. The effects of base metal composition and the surface condition of the base metal were also studied and found to affect the detachability of slag both physically and chemically. When changing from steel base metal to a nickel-based alloy, detachability worsened significantly. This effect was related to the presence of chromium in the nickel-based alloy (16 wt% Cr) compared with the steel base metal (1.35 wt% Cr) which results in a chemical effect because of the formation of chromium spinels as reaction products as noted above. However, when comparing different steel base metals with little or no chromium the difference in slag detachability was attributed to the base metals' thermal contraction characteristics. The experimental observations on detachability and the results of dilatometric measurements confirmed that the use of absolute values of the coefficients of thermal expansion of slag and base metal to determine which flux composition will provide easy detachability can be erroneous. The mean integrated differential thermal contraction of the slag-metal systems were evaluated from the softening temperature of the slag to 30 C. A comparison of the detachability of slags from welds made on mild steel (1010 steel) base metal and HY80 base metal (quenched and tempered martensitic steel) showed that the integrated differential thermal contraction per unit length was smaller with mild steel base metal than with HY80 base metal and that the slags of corresponding welds were more difficult to detach in the case of the mild steel base metal. This correlation of integrated differential thermal contraction per unit length with detachability was found to be valid only in the cases of slags with microcrack-free structures. Furthermore, the cooling rate of the slag-metal system has an effect on the detachability. The higher the cooling rate, the poorer the detachability. The surface condition of the base metal, that is whether descaled or scaled, was found to affect the detachability of the slag. Scaled base metal provided slags that were more difficult to detach than the slags from a thoroughly descaled base metal under the same conditions of welding. This deleterious effect was attributed to the formation of a chemical bond when the molten slag dissolves the scale and forms a glass. Also, the presence of scale will increase the oxidizing potential of the slag making it easier to oxidize deleterious elements like chromium in the base metal (even when the base metal is low in chromium). The general findings of this work show that chemical effects due to slag-metal reactions are more important than physical effects of differential thermal expansion. However, in the absence of chemical effects the differential thermal contraction (expansion) is a more useful indicator of ease of detachability than the absolute value of the coefficient of thermal expansion of the slag or weld metal. Also, the correlation of differential thermal contraction with detachability of slag has to be done with the knowledge of the structure of the slags in question. Finally, the chemical composition of the base metal and its surface condition are also important factors that affect the degree of slag detachability.

"Visible light emission during gas tungsten arc welding," Euiwhan Kim, Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomsa W. Eagar, pp.131, 1986.

"A study of the wetting of alumina by silver-based active metal braze alloys," Edward Scott Podszus, Thesis (B.S.)--Massachusetts Institute of Technology, Dept. of Mechanical Engineering, supervised by Thomas W. Eagar, pp.71, 1986.

"Transport processes affecting the shape of arc welds," Min-Long Lin, Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp.188, 1985.

"Digital signal processing as a diagnostic tool for gas tungsten arc welding," Carl David Sorensen, Thesis (Ph.D.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp.167, 1985.

"Metal vapors in gas tungsten welding arcs," Gregory Joseph Dunn, Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp.196, 1984.

"Resistance spot welding of galvanized steel sheet," Steven Anthony Gedeon, Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, supervised by Thomas W. Eagar, pp.253, 1984.
Abstract: Methods of measuring the hydrogen content of Gas Metal Arc Welds (GMAW) are evaluated. The recently developed American Welding Society standard A4.3-86 using gas chromatography was found to measure the relevant content with reasonable reproducibility, whereas the IIW specification does not. The amount of hydrogen absorbed by Gas Metal Arc Welds as a function of percent H20, O2 and CO2 added to the argon weld shielding gas is quantified. Sievert's law is shown to be invalid for modeling the amount of hydrogen initially absorbed by the molten weld pool. A new model is postulated based on the hypothesis that diatomic hydrogen will dissociate in the cathode boundary layer at a different reaction temperature than  the hydrogen absorption reaction which occurs at the temperat